Organic Chemistry II
Code
7095
Academic unit
Faculdade de Ciências e Tecnologia
Department
Departamento de Química
Credits
6.0
Teacher in charge
Luísa Maria da Silva Pinto Ferreira
Weekly hours
4
Total hours
63
Teaching language
Português
Objectives
Complementary basic formation on Organic Chemistry
Prerequisites
Organic Chemistry I
Subject matter
The electromagnetic spectrum. Kinds of spectroscopy. 1H-NMR spectroscopy, IR and UV-Vis. Mass spectrometry. Application examples.
Conformational analysis. Conformation vs. Configuration. Conformation of linear and cyclic.
saturated and unsaturated compounds .
Nucleophilic substitution reactions on saturated carbon. Nucleophilic aliphatic substitution: SN1 and SN2 mechanisms.
Elimination reactions. Mechanisms E1 and E2. Substitution versus elimination. Mechanism E1cb.
Unsaturated compounds as nucleophiles. Electrophilic addition. Electrophilic addition to conjugated dienes. Cycloaddition. Diels-Alder reaction.
Formation and reactions of enols and enolates. Tautomerism. The aldol reaction.
Reactivity of aromatic compounds. Electrophilic aromatic substitution reactions. Nucleophilic aromatic substitution reactions. Mechanisms of addition-elimination and elimination-addition. Diazonium salts.
Bibliography
Livro recomendado:·
Clayden, J.; Greeves, N.; Warren, S.; Wothers, P. “Organic Chemistry”, Oxford University Press, 2nd Ed., 2012.
Complementary bibliography:
Santos, P. P., “Química Orgânica volume I e II”, IST Press, 1ªedição, 2011.
March, J. “Advanced Organic Chemistry”, Wiley Interscience, 6ª Ed., 2007.
Evaluation method
Score laboratory component 35%
Score written component 65%