Faculdade de Ciências e Tecnologia

Diagnosis and Conservation of Stone

Code

7417

Academic unit

Faculdade de Ciências e Tecnologia

Department

Departamento de Conservação e Restauro

Credits

6.0

Teacher in charge

Maria Amélia Alves Rangel Dionísio

Weekly hours

5

Total hours

70

Teaching language

Português

Objectives

At the end of this course the student will have acquired knowledge, skills and competences  to:

 

  • to identify the problems that affect the exposed stone materials, to characterise and interpret them and to propose solutions for the identified problems,
  • to enable the student to acquire knowledge: i) on the genesis, properties and specificities of the materials under study, ii) on the degradation phenomena and on the driving mechanisms, iii) on the interpretation of the onsite behaviour of each specific material,  on their decay products and the methods of diagnosis.
  • to approach the methods of conservation and restoration, enabling the student to acquire knowledge on the basic procedures of the profession through the study of treatment methods and products as well as the methods used in their study, in the lab and onsite,
  • the information is illustrated with results taken from research studies and from real case-studies.   

Prerequisites

Good knowledge previously acquired in the course "Principles of Geology and Mineralogy"

Subject matter

 

Brief presentation of the curricular unity

 Students presentation.

Aims of the curricular unity. Evaluation system.

Brief Introduction to Portugal Geology

 

Relationship between stone used in Cultural Heritage and the portuguese geological unities.

 

Main Construction Materials

Stone, mortars, ceramics, glass, metals, wood. Traditional materials versus modern materials. Lime, gypsum, cement, pozoolans and organic products.

Structural Materials and Ornamental Materials

Types of Stone masonary

 

 

Limestones

Mineralogical composition; clay minerals. Hardness, porosity and mechanical strenght.

Granites

Mineralogical composition;  primary and secundary minerals. Porous system  mechanical strenght and permeability. Anisotropy.

Marbles

Metamorphism and mineralogical composition. Porous and fissure system.Relevant Properties.

Schists

Mineralogical composition and anisotropy. Chemical resistance and physical fragility.

Rock weathering

Weathering and degradation of mnaterials

Natural rock weathering: meteoric weathering or deuteric weathering.

Weathering and weatheribility.

Intrinsic weathering (the case of granites). Weatjhering as a chemical  process of  reaching equlibrium.

Weathering mechanisms: chemical and physical.

Silicates weathering. Hydrolisis. Goldisch series. Weathring due to cooling and exposition to weather agents. Contrast between feldspars and quartz behaviour. Thermal expansion. Clay minerals expansion.

Intrinsic versus extyrinsic factors.

 

Decay of materials when applied in workmanship

Environmental factors. Water as the main factor. Temperature, relative humidity, exposition. Construtive factors.

Association of diferent materials. Compatibility of properties.

Capillary rise and soluble salts.

Atmospheric pollution

Gases and paticles. Industrial and urban pollution. Sulphur and nitrogen compounds. Dry and wet deposition. Sazonal variation. Marine spray.

Limestones

Decay forms; black crusts: nature, formation mechanisms, conservation consequences. Alveolar decay and soluble salts.

Granites

Decay forms; black cruts and ferrous films. Plaquettes nad granular desintegration.

Marbles

Decay forms. Plaques and sugaring. Calcite thermal behaviour, importance of crystals dimensions. Dissolution.

Schists

Decay forms. esfoliation.

Biological colonization

Aerial plants. Lichens and algae. Fungii and bacteria. Interaction with stone.

Conservation. General aspects of diagnosis

Identification of decay causes

Materials identification: macroscopic inspection, optical microscopy and SEM, chemical and physical-chemical methods, XRD, TGA, ATD, etc.

Sampling

Representative samples. Dimension of samples. Stone sampling in outcrops and monuments.

Laboratory Methods

Petrography and mineralogy. Thin sections.

Physical properties (porosity, density, mechanical strenght, expansibility, etc.). Porosimetry.

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Enironmental Characterization

Temperature, relative humidity,  rain and air composition. Climate and microclimate.

Identification of decay products

Visual inspection and optical fiber microscopes. Non-destructive tests. Ultrasounds; termography. Encoscopy. Georadar. Microdrilling.

Definition of a test program

Adaptation to each case and to each stone material

Stone conservation: main types of intervention

Cleaning, consolidation, protection

Brief presentation of each category. Reasons for its accomplishment.

Black crosts and biological colonization: decay or aestetic factors?

Powdreing and arenizatrion: strenght and strctural stability degradation.

Very porous stones applied outdoors and their protection.

Methods evaluation criteria

Eficiency,  harmfullness and durability. Reversibility or retreatability.

Preliminary operations

Causes identification. Aims definition. Theoritical  framing of conservation operations.

 Real situation of pratical conservation

Safe solutions or  of badly lesser?  Importance of previous experiences. Limitation of conservation operations. Importance of maintenace operations.

Cleaning of stone surfaces

Distinction between crust and superficial deposit

Different process phases (daignostic, negotiation, execution).

Substrate Properties (petrographic type, decay state, hardness and mechanical strenght).

Dirtiness characteristics (type, coehsion, thickness).

Current Cleaning Methods

Soft versus agressive methods. Requisites that must be respected

Non-removable of original materials and patina conservation as a security measure of non agressiveness.  Abscence of collateral damage.

Water Cleaning

Forms of use: drained, pressurized, vapor. Risks of infiltrations and mobilization of  soluble salts.

 

Cleaning with abrasive methods

Sand blasting (dry or wet)

 

Claening with laser radiation

Brief presentation of the cleaning mechanism by fotonic abalation. Types of lase. The importance of  beam transport way.

 

Conservation treatments

Consolidants and hydrofugues

Main products families

Laboratory studies versus in-situ studies. Advantages and limitations.

Description of some used methods of assay in these studies.

Consolidants

Efficiency: depth of penetration and mechanical strenght. Methods of laboratory for its determination.

Harmfullness: contrast of resistance and formation of interfaces; permeability to the vapor; chromatic variations.

 Durability: assays of accelerated aging and in natural exposition;

 Biocide Treatments

Evaluation of efficiency. Study cases. Recolonization monitoring

 Documentation of conservation interventations

Main stages

Previous documentation to intervention

Cartographic essays

Mapping of decay conservation

Lexic of decay forms

Documentation of operations performed

Documentation of products and apllication methods

Documentation of  final result of intervention

Maintenance plans or preventive conservation

Pratical examples of conservation intervention case studies in limestones

  -Aims, Study methods, some results

 

· Santa Cruz Church, in Coimbra.

· - Belém Tower

· Jerónimos Monastery Cloister

· Évora Cathedral

· Porta Especiosa, Coimbra

 

 

 

 

 

 

 

 

 

 

 

Teaching method

Exposition based on examples from investigation or pratical case studies of conservation and restoration.

Observation of samples from materials and visit to real case studies where materials and decay problems are presented and where forms of identification of decay are explained.

Caracterisation of materials properties based on laboratorial instrumentations, namely of:

- samples of stone deterioration forms

- stone samples in sound, or weathered, or treated state

Visit to workmanships whre great stone intervations were done  and where it is possible to illustrate conservation techniques and to explain why they were choosed.

Evaluation method

1. Final exam, or three parcial tests, covering the full programme of the discipline (60% final note)

2. Report of laboratorial work + report of field work about the diagnosis of a study case (30% final note)

3. Study of articles + questionnaires or descriptions about study trips + exercises made in the practical lessons (10% final note)

Courses